Chemistry and structure of core/double-shell nanoscale precipitates in Al–6.5Li–0.07Sc–0.02Yb (at.%)

An Al–6.3Li–0.07Sc–0.02Yb (at.%) alloy is subjected to a double-aging treatment to create nanoscale precipitates, which are studied by atom-probe tomography and transmission electron microscopy. After homogenization and quenching, Yb atoms form clusters exhibiting L12-like order. A first aging step at 325 C leads to a doubling of microhardness as a result of the formation of coherent precipitates with an Al3Yb-rich core and an Al3Sc-rich shell. The core and shell both exhibit the L12 structure and both contain a large concentration of Li, which substitutes for up to 50% of the Sc or Yb atoms at their sublattice positions. These core/single-shell precipitates provide excellent resistance to overaging at 325 C. Subsequent aging at 170 C increases the microhardness by an additional 30%, through precipitation of a metastable d-Al3Li second shell on the core/single-shell precipitates, thereby forming a chemically and structurally complex core/double-shell structure. The metastable d-Al3Li phase is observed to form exclusively on pre-existing core/shell precipitates. 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.